Most Gigabyte boards have USB charging feature, older Asus boards had a jumper allowing you to set the +5V USB source from 5Vsb instead of the main +5V line, If your motherboard does not offer this feature, it is not really possible.
If you need to power devices that need data connection to the PC and standby power for charging/operation, you can consider a small powered USB hub. This will keep the devices charged and when the PC is awake, the data connection will be active as well.