CPU/Mobo When do we add/upgrade RAM?

nightHawk12

Novice
My system : b550+5600+6600xt with 2x8GB CL18 3600Mhz

On startup 5.2GB is already gulped down by WIndows 11. chrome consumes around 1.5GB and when gaming(Valorant) I have like 3-4GB free memory.Should I extend it to 32GB RAM by adiing 2 more 8GB sticks or just buy two more 16GB sticks incase 64GB becomes the new norm.
 
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