dual channel mode will only work for same spec DIMMS only,2 sets to be 100% identical.
Enabling Dual Channel
In order to enable dual channel technology you need to have:
Compatible chipset and motherboard (Intel CPU) or compatible CPU (AMD).
Two or four identical memory modules, compatible with the technology supported by the motherboard (DDR-SDRAM, DDR2-SDRAM or DDR3-SDRAM).
If you have only one memory module dual channel isn’t available. So if you want a PC with 2 GB of RAM the best way to achieve this is by using two 1 GB modules instead of one single 2 GB module, because on the first case you can enable dual channel mode (which increases performance), while on the second you can’t.
If your motherboard has only two memory sockets – which is more common to happen with entry-level motherboards – then to enable dual channel you have to simply install two memory modules.
On motherboards with four memory sockets, which is the most common scenario, the correct way to enable dual channel technology varies.
If you have four memory modules simply install all of them and dual channel method will be enabled.